Boronic acid building blocks: tools for self assembly
Boronic acid building blocks: tools for self assembly
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DOI：
10.1039/c0cc02921a
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Fossey, John S.
中科院分区：
文献类型：
--
作者：
Nishiyabu, Ryuhei;Kubo, Yuji;Fossey, John S.
动态共价官能度被认为是构建有序结构的有力工具，可逆的性质在化学上促进了自我控制和自我校正。硼酸与二醇及其同系物的络合作用在实现和开发具有动态共价官能度的可逆含硼多组分体系方面已经显示出巨大的前景。结构导向潜力导致了各种自组织的发展，不仅涉及大环，笼和胶囊，但也多孔共价有机框架和聚合物。这篇专题文章重点介绍了结构控制和卓越的合成。
Dynamic covalent functionality has been acknowledged as a powerful tool for the construction of organised architectures, the reversible nature thermodynamically facilitates self-control and self-correction. The use of boronic acids complexation with diols and their congeners has already shown great promise in realising and developing reversible boron-containing multicomponent systems with dynamic covalent functionality. The structure-directing potential has lead to the development of a variety of self-organisation involving not only macrocycles, cages and capsules, but also porous covalent organic frameworks and polymers. Structure controls as well as remarkable synthesis are highlighted in this feature article.