Highly selective acylation of alcohols and amines by an indium triiodide-catalysed transesterification process
Highly selective acylation of alcohols and amines by an indium triiodide-catalysed transesterification process
复制标题
三碘化铟催化的酯交换过程对醇和胺进行高选择性酰化
DOI：
10.1039/b002181o
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发表时间：
2000
期刊：
影响因子：
--
通讯作者：
A. Sarkar
中科院分区：
文献类型：
--
作者：
B. Ranu;P. Dutta;A. Sarkar
研究了三碘化铟催化的酯交换反应中乙酸乙酯与醇和胺的酰化反应。使用该方法，在仲OH和酚OH基团存在下的伯OH基团的酰化，以及在仲NH和伯OH存在下的伯NH2的酰化已经以高选择性实现。
A very simple method has been developed for the acylation of alcohols and amines by ethyl acetate through an indium triiodide-catalysed transesterification process. Using this method acylation of a primary OH group in the presence of secondary and phenolic OH groups, and of a primary NH2 in the presence of secondary NH and primary OH have been achieved with high selectivity.