Formation of novel organogels by the addition of phenols to AOT micelles in isooctane
Formation of novel organogels by the addition of phenols to AOT micelles in isooctane
复制标题
通过将酚添加到异辛烷中的 AOT 胶束中形成新型有机凝胶
DOI:
10.1021/j100145a038
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发表时间:
1993
期刊:
影响因子:
--
通讯作者:
G. McPherson
中科院分区:
文献类型:
--
作者:
Xiaodong Xu;M. Ayyagari;Murthy Tata;V. John;G. McPherson
We report the formation of novel organogels through the addition of stoichiometric amounts of specific phenols to the anionic surfactant, AOT, dispersed in isooctane. The gel is formed at concentrations of the surfactant and the phenolic constituent as low as 0.1 M. FTIR data indicate hydrogen bonding between the surfactant and the phenolic species and also show evidence of conformational changes in AOT subsequent to gel formation. A novel aspect is the transition from the gel to the liquid state upon exposure to trace amounts of moisture