Microporous Structure of a Chain Compound of Copper(II) Benzoate Bridged by Pyrazine

Microporous Structure of a Chain Compound of Copper(II) Benzoate Bridged by Pyrazine
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吡嗪桥联苯甲酸铜(II)链状化合物的微孔结构

DOI:
10.1246/cl.1999.367
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发表时间:
1999
期刊:
影响因子:
1.6
通讯作者:
H. Naono
H. Naono
中科院分区:
化学4区
文献类型:
--
作者:
Ryoji Nukada;W. Mori;S. Takamizawa;M. Mikuriya;M. Handa;H. Naono

文献摘要

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苯甲酸铜(II)与吡嗪(PYZ)反应生成具有气体封闭性质的化合物[Cu2(BZ)4(PYZ)]n(1)。X-射线结构分析表明,1·2nCH3CN是由链组成的微孔结构,其中羧酸二聚体单元由吡嗪分子连接。
Reaction of copper(II) benzoate with pyrazine (pyz) gave a compound, [Cu2(bz)4(pyz)]n (1) which has a gas-occlusion property. The X-ray structure analysis of 1·2nCH3CN shows a microporous structure formed by chains where the carboxylate dimer units are linked by pyrazine molecules.