Spectroscopic Study of a Europium Luminescent Complex Adsorbed on Si-Ti Inorganic–Organic Hybrid
Spectroscopic Study of a Europium Luminescent Complex Adsorbed on Si-Ti Inorganic–Organic Hybrid
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DOI：
10.1006/jcis.2001.7819
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发表时间：
2001-11
影响因子：
9.9
通讯作者：
R. Farias;S. Alves;M. Belian;G. F. Sá
中科院分区：
文献类型：
--
作者：
R. Farias;S. Alves;M. Belian;G. F. Sá
Abstract Through the sol–gel process, a silicon–titanium inorganic–organic hybrid is synthesized and used as substrate to study the adsorption and spectroscopy of a europium luminescent complex: Eu(fod)3. The complex and silicon–titanium hybrid were mixed in stoichiometric amounts to produce samples with 1%, 5%, and 10% (m/m) of adsorbed complex, with the matrices being pressed at 380 mPa for 0.5, 30, and 60 min before spectroscopic analysis. It is verified that the intensity of the 5D0→7F2 emission band is dependent on the complex/nitrogen ratio and almost independent of the external pressure.
