Uniform and simultaneous orthogonal functionalization of a metal–organic framework material
Uniform and simultaneous orthogonal functionalization of a metal–organic framework material
复制标题
金属有机骨架材料的均匀同步正交功能化
DOI：
10.1039/c9me00182d
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发表时间：
2020
影响因子：
3.6
通讯作者：
Gadzikwa, Tendai
中科院分区：
文献类型：
--
作者：
Samarakoon, Kanchana P.;Yazdanparast, Mohammad S.;Day, Victor W.;Gadzikwa, Tendai
我们利用正交化学反应性来生成均匀的多功能密闭空间。在明确位置具有叠氮化物和羟基反应基团的金属有机框架（MOF）材料可通过多种途径（包括同时进行的一锅反应）独立官能化以产生均匀双官能化材料。
We exploit orthogonal chemical reactivity to generate uniformly multifunctionalized confined spaces. A metal–organic framework (MOF) material that has azide and hydroxyl reactive groups in well-defined locations is independently functionalized to yield a uniformly bifunctionalized material via multiple paths, including via a simultaneous, one-pot reaction.