PROPYLENE OXIDE ROUTES TAKE OFF
PROPYLENE OXIDE ROUTES TAKE OFF
复制标题
环氧丙烷路线起飞
DOI：
10.1021/cen-v084n041.p022
复制
发表时间：
2006
影响因子：
1.5
通讯作者：
P. Short
中科院分区：
文献类型：
--
作者：
A. Tullo;P. Short
当巴斯夫的尤尔根·汉布雷希特和安德鲁·N。世界上最大的两家化学公司的负责人陶氏化学公司的利文斯会面，为一家新的化工厂破土动工，这可以被解读为对该工厂的技术将发挥作用的信心的强烈声明。上个月底，两位主席在比利时安特卫普开工建设环氧丙烷工厂。这是陶氏化学和巴斯夫的合资企业，是两家可能成为世界上第一家使用过氧化氢生产环氧丙烷的工厂之一，德固赛支持另一家。这项技术被称为HPPO，旨在将环氧丙烷从副产品的产生或与氯碱生产的高度整合中解放出来。乍一看，这种解放似乎是一项容易的任务。多年来，化学工业已经能够直接将乙烯氧化成环氧乙烷。但丙烯有更大的...
WHEN JURGEN HAMBRECHT of BASF and Andrew N. Livens of Dow Chemical, the heads of the world's two largest chemical companies, meet to break ground for a new chemical plant, it can be read as a strong statement of confidence that the plant's technology will work. The two chairmen were on hand in Antwerp, Belgium, late last month to launch construction of a propylene oxide facility. A joint venture between Dow and BASF, it is one of two plants—Degussa is backing the other one—that may become the world's first to use hydrogen peroxide to make propylene oxide. This technology, called HPPO, is meant to free propylene oxide from the creation of coproducts or from heavy integration with chlor-alkali production. At first glance, this liberation might seem like an easy task. For years, the chemical industry has been able to directly oxidize ethylene into ethylene oxide. But propylene has a greater ...