An Effective Heterogeneous Ozone-Based Advanced Oxidation Process in Acidic Solution— Ti-MCM-41/H2O2/O3
An Effective Heterogeneous Ozone-Based Advanced Oxidation Process in Acidic Solution— Ti-MCM-41/H2O2/O3
复制标题
酸性溶液中有效的非均相臭氧高级氧化工艺——Ti-MCM-41/H2O2/O3
DOI:
10.1080/01919512.2015.1113854
复制
发表时间:
2016
期刊:
影响因子:
--
通讯作者:
Chun’an Ma
中科院分区:
文献类型:
--
作者:
Ruofan Peng;Tongdong Shen;S. Tong;Chun’an Ma
ABSTRACT A useful ozone-based advanced oxidation process in acidic solution- Ti-MCM-41/H2O2/O3 was studied, and acetic acid (HAc) was selected to be degraded because it is a hydroxyl radical-probe compound in ozonation. The results showed that only Ti-MCM-41/H2O2/O3 could effectively degrade HAc at initial pH 3.0, and that other oxidative processes such as O3, H2O2/O3 Ti-MCM-41/O3 and MCM-41/H2O2/O3, all could not, indicating the coexistence of Ti-MCM-41 and H2O2 was necessary for the generation of hydroxyl radicals under the experimental conditions. The optimization of parameters indicated that the rate of generation of hydroxyl radicals could be regulated by the amount of Ti-MCM-41, and that the amount of hydroxyl radicals could be controlled by the concentration of H2O2. The preceding results are of significance for effective treatment of acidic refractory wastewater.
影响因子:
7.4
作者:
BABBS, CF;GRIFFIN, DW
通讯作者:
GRIFFIN, DW