Visible-light induced oxidative Csp3–H activation of methyl aromatics to methyl esters
Visible-light induced oxidative Csp3–H activation of methyl aromatics to methyl esters
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DOI：
10.1039/c6gc01880g
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发表时间：
2016-09
期刊：
影响因子：
9.8
通讯作者：
Lingling Zhang;Hong Yi;Jue Wang;A. Lei
中科院分区：
文献类型：
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作者：
Lingling Zhang;Hong Yi;Jue Wang;A. Lei
在温和条件下直接官能化容易获得的碳氢化合物满足了绿色和可持续化学的要求。在这项工作中，利用 O2 通过光催化实现了甲基芳烃的温和绿色催化氧化 Csp3-H 活化。可以耐受大量甲基芳烃，为芳香族羧酸甲酯提供了一条绿色路线。此外，该协议可以在克规模上执行。
Direct functionalization of readily available hydrocarbons under mild conditions fulfills the requirements of green and sustainable chemistry. In this work, a mild and green catalytic oxidative Csp3–H activation of methyl aromatics using O2via photocatalysis has been achieved. A lot of methyl aromatics can be tolerated, providing a green route for aromatic methyl carboxylates. In addition, this protocol can be performed on a gram scale.