Let's Sort It Out: Self-Sorting of Covalent Organic Cage Compounds
Let's Sort It Out: Self-Sorting of Covalent Organic Cage Compounds
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DOI：
10.1055/s-0035-1561364
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发表时间：
2016-05-01
期刊：
影响因子：
2
通讯作者：
Dhara, Ayan
中科院分区：
文献类型：
--
作者：
Beuerle, Florian;Klotzbach, Stefanie;Dhara, Ayan
小而刚性前体的动态共价自组装成笼型结构可以作为形成分子多孔单元的有力策略。为了增强这类纳米结构的功能，需要形成具有高空间精度的复杂多组分组件，以及可逆组装和拆卸的按需控制。在这里，我们重点介绍了我们最近在一系列共价有机笼化合物的尺寸特异性合成和自分类特性以及由硼氮添加键组装的超分子笼的刺激响应组装方面的一些最新成就导论2共价有机笼的自分选3刺激反应笼4结论与展望
Dynamic covalent self-assembly of small and rigid precursors into cage-type architectures can serve as a powerful strategy for the formation of molecular porous units. In order to enhance the functionality of suchlike nanostructures, formation of complex multicomponent assemblies with high spatial precision, and on-demand control of both reversible assembly and disassembly is highly desirable. Here we highlight some of our most recent achievements on the size-specific synthesis and self-sorting properties within a series of covalent organic cage compounds and the stimuli-responsive assembly of supramolecular cages assembled by boron-nitrogen dative bonds.1 Introduction2 Self-Sorting of Covalent Organic Cages3 Stimuli-Responsive Cages4 Conclusion and Outlook