Texture analysis of thick bismuth ferrite lead titanate layers
Texture analysis of thick bismuth ferrite lead titanate layers
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铁酸铋厚钛酸铅层的织构分析
DOI:
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发表时间:
2014
期刊:
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通讯作者:
A. Bell
中科院分区:
文献类型:
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作者:
M. Palizdar;D. Mallick;T. Maity;Saibal Roy;T. Comyn;T. Stevenson;C. Fancher;Jacob L. Jones;S. Poterala;G. Messing;E. Suvacı;A. Kleppe;Andrew J. Jehcoat;A. Bell
The template grain growth technique was used to synthesis textured 60BiFeO3-PbTiO3(60:40BFPT) by using platelets of BaTiO3 as template. Synchrotron measurement clearly showed textured 60:40BFPT. Moreover, in situ high energy synchrotron radiation was employed to investigate the influence of an external electric filed on crystallographic structure of mixed phase 60:40BFPT. Application of an electric field ≥ 1 kV/mm resulted in phase transformation from mixed rhombohedral/tetragonal phases (≈ 73.5% tetragonal / 26.5% rhombohedral) to predominately tetragonal phase (≈ 95%) at applied field of 6 kV/mm. A crystallographic texture refinement was done by using software package materials analysis using diffraction (MAUD) with a 4th order spherical harmonic orientation distribution function (ODF). This refinement was completed using a P4mm+Cm structure model. Texture coefficients were constrained such that the equivalent texture coefficients of each phase are the same. The resulting texture refinement determined that sample has a 1.3 multiples of random distribution (MRD) {100} crystallographic texture.