2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine( v ) oxidant
2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine( v ) oxidant
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2-碘氧基苯甲酸二三氟甲磺酸盐：最强的高价碘（v）氧化剂
DOI：
10.1039/c9cc04203b
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发表时间：
2019
影响因子：
4.9
通讯作者：
Zhdankin, Viktor V.
中科院分区：
文献类型：
--
作者：
Yusubov, Mekhman S.;Soldatova, Natalia S.;Postnikov, Pavel S.;Valiev, Rashid R.;Yoshimura, Akira;Wirth, Thomas;Nemykin, Victor N.;Zhdankin, Viktor V.
以2-碘氧基苯甲酸(IBX)为原料，通过与三氟甲磺酸反应合成了IBX的双硫代衍生物，并用单晶X-射线单晶衍射法对其进行了表征。IBX-Ditriflate是一系列结构相似的IBX衍生物中最强大的氧化剂，其对碳氢化合物和抗氧化多氟醇的氧化能力是最好的证明。
A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.