Statistical mechanical deconvolution of thermal transitions in macromolecules. I. Theory and application to homogeneous systems

Statistical mechanical deconvolution of thermal transitions in macromolecules. I. Theory and application to homogeneous systems
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大分子热转变的统计机械反卷积。

DOI:
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发表时间:
1978
期刊:
影响因子:
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通讯作者:
R. Biltonen
R. Biltonen
中科院分区:
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文献类型:
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作者:
E. Freire;R. Biltonen

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The theoretical basis for the statistical mechanical deconvolution of a thermally induced macromolecular melting profile is presented. It is demonstrated that all the thermodynamic quantities characterizing a multistate macromolecular transition can be obtained from the average excess enthalpy function, 〈ΔH〉, of the system, without any assumption of the particular model or mechanism of the reaction.