Organolanthanide-centered hydroamination/cyclization of aminoolefins. Expedient oxidative access to catalytic cycles
Organolanthanide-centered hydroamination/cyclization of aminoolefins. Expedient oxidative access to catalytic cycles
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DOI：
10.1021/om00156a005
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发表时间：
1990-06
期刊：
影响因子：
2.8
通讯作者：
M. Gagné;S. Nolan;T. Marks
中科院分区：
文献类型：
--
作者：
M. Gagné;S. Nolan;T. Marks
易接近的（Me{sub 5}C{sub 5}）{sub 2}Sm和（Me{sub 5}C{sub 5}）{sub 2}Sm(THF){sub 2}催化多种氨基烯烃的氢胺化/环化。机理观察表明，活性催化剂是三价有机钐配合物
The readily accessible (Me{sub 5}C{sub 5}){sub 2}Sm and (Me{sub 5}C{sub 5}){sub 2}Sm(THF){sub 2} catalyze the hydroamination/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organosamarium complexes