Fabrication of low-melting glasses in the ZnSO4 -KPO3 - NaPO3 and Li2SO4 - Na2SO4 - K2SO4 - NaPO3 Systems
Fabrication of low-melting glasses in the ZnSO4 -KPO3 - NaPO3 and Li2SO4 - Na2SO4 - K2SO4 - NaPO3 Systems
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在 ZnSO4 -KPO3 - NaPO3 和 Li2SO4 - Na2SO4 - K2SO4 - NaPO3 系统中制造低熔点玻璃
DOI：
10.1007/bf01166029
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发表时间：
1996
影响因子：
0.6
通讯作者：
V. L. Mmamoshin
中科院分区：
文献类型：
--
作者：
V. L. Mmamoshin
本文研究了ZnSO_4-KPO_3-NaPO_3和Li_2SO_4-Na_2SO_4-K_2SO_4-NaPO_3系统的低熔玻璃。据确定，我更广泛的我所谓的阳离子分类，即，体系中Rn+阳离子的数量越多，玻璃形成的可能性越大，越容易形成。结果表明，低熔点玻璃中结构形成过程的发生在很大程度上取决于弱分子间相互作用力。因此，所研究的玻璃具有独特的性质，即低熔点，低化学稳定性和极高的TCLE（超过300 × 10−7 K−1）
Low-melting glasses of the ZnSO4-KPO3 -NaPO3 and Li2SO4 -Na2SO4 K2SO4 -NaPO3 systems are investigated. It is established that me wider me so-called cation assortment, i.e., the greater the number of cations Rn+ in the system, the more probable and the easier is the glass formation. It is shown that the occurrence of the processes of structure formation in low-melting glasses depends considerably on the forces of weak intermolecular interaction. For this reason, the investigated glasses have unique properties, namely, are low-melting and have low chemical stability and an anomalously high TCLE (over 300 × 10−7 K−1)