The microstructure and martensitic transformation behaviors in Ti-Ni-Hf -X (Ag, Sn) high temperature shape memory alloys

The microstructure and martensitic transformation behaviors in Ti-Ni-Hf -X (Ag, Sn) high temperature shape memory alloys
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Ti-Ni-Hf-X(Ag,Sn)高温形状记忆合金的显微组织和马氏体相变行为

DOI:
10.1016/j.jallcom.2018.05.043
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发表时间:
2018-08
影响因子:
6.2
通讯作者:
Cai Wei
Cai Wei
中科院分区:
材料科学2区
文献类型:
--
作者:
Yi Xiaoyang;Pang Guobo;Sun Bin;Meng Xianglong;Cai Wei

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The microstructures and martensitic transformation behaviors of the quaternary Ti-Ni-Hf-X (Ag, Sn) high temperature shape memory alloys were investigated systematically. The results showed that Ag and Sn were soluble in Ti–Ni-Hf matrices with a limited solubility of 0.28 at.% and 1.78 at.%, respectively. In addition to the martensite and (Ti,Hf)2Ni phase, the pure elemental Ag particle was also observed in the Ti-Ni-Hf-Ag alloys. However, the excessive Sn addition resulted in the formation of the intermetallics such as Ti3Sn type and TiNi2Sn type phase in the Ti-Ni-Hf-Sn alloys. Moreover, with the increasing of Sn content, the amounts of (Ti,Hf)2Ni phases decreased owing to the dissipation reaction of 12(Ti,Hf)2Ni +8Sn → 6TiNiHf + 5(Ti,Hf)3Sn + 3(Ti,Hf)Ni2Sn. Single martensitic transformation corresponding to B2⇋B19′ was observed in Ti-Ni-Hf-Ag alloys. While the Ti-Ni-Hf-Sn alloys with the higher Sn content (≥2 at.%) were characterized by two-steps martensitic transformation during the heating process. Both Sn and Ag addition reduced the martensitic transformation temperatures.
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