Specific Enhancement of Activity of Carbon-supported Single-site Co Catalyst in the Microwave-assisted Solvent-free Aerobic Oxidation
Specific Enhancement of Activity of Carbon-supported Single-site Co Catalyst in the Microwave-assisted Solvent-free Aerobic Oxidation
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DOI：
10.1246/cl.170118
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发表时间：
2017-03
影响因子：
1.6
通讯作者：
Takeharu Yoshii;Kazuki Nakatsuka;Yasutaka Kuwahara;K. Mori;H. Yamashita
中科院分区：
文献类型：
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作者：
Takeharu Yoshii;Kazuki Nakatsuka;Yasutaka Kuwahara;K. Mori;H. Yamashita
研究了微波辐射下无溶剂乙苯有氧氧化反应中碳载钴催化剂的结构与活性关系。与常规加热相比，在微波辐射下，单中心Co物种显示出特别高的催化活性，而当使用Co纳米颗粒催化剂时，微波不会加速氧化。
The structure–activity relationship of carbon-supported Co catalysts was investigated in solvent-free aerobic oxidation of ethylbenzene under microwave irradiation. A single-site Co species show specifically high catalytic activity under microwave irradiation compared to conventional heating, while the oxidation is not accelerated by microwave when Co nanoparticle catalysts are used.