The structure of glass

The structure of glass
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玻璃的结构

DOI:
10.1016/0022-3093(77)90091-6
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发表时间:
1977
期刊:
影响因子:
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通讯作者:
E. A. Porai
E. A. Porai
中科院分区:
--
文献类型:
--
作者:
E. A. Porai

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这就是列别捷夫在1921年提出的第一个玻璃结构假说,它使研究玻璃态的物理学家和化学家们担心和争论了几十年。这一假说首先引起了当时对玻璃完全同质性的怀疑,并指出了在玻璃结构与其性质之间建立关系的可能性,以及通过改变结构来改变性质的可能性。在1974年的第十届国际玻璃大会上,Zarzycki作了一份精彩的报告,他在报告中提出了玻璃态二氧化硅的”畴结构”假说。1972年,Patel等人/ 2/得出结论,在玻璃中存在密度为2.32 g/cm 3的有序二氧化硅区域,
Such was the first hypothesis of glass structure suggested by Lebedev in 1921 which made physicists and chemists investigating the vitreous state worry and argue for several decades. This hypothesis first aroused a heretical for that time doubt in full homogeneity of glass and indicated the possibility of establishment of a relation between the structure of glass and its properties, the possibility to change the properties by changing the structure. At the Tenth International Congress on Glass in 1974 Zarzycki made a brilliant report/1/in which he suggested the hypothesis of a" domain structure" of vitreous silica. In 1972 Patel et al./2/came to the conclusion about the existence in glasses of regions of ordered silica with a density of 2.32 g/cm 3,