Small molecule activation at uranium coordination complexes:: control of reactivity via molecular architecture
Small molecule activation at uranium coordination complexes:: control of reactivity via molecular architecture
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DOI：
10.1039/b513755c
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发表时间：
2006-01-01
影响因子：
4.9
通讯作者：
Meyer, K
中科院分区：
文献类型：
--
作者：
Castro-Rodríguez, I;Meyer, K
富电子铀配合物对小分子显示出明显的反应性。在这篇专题文章中，三价铀离子与经典的沃纳型配体环境协调的激发化学进行了综述。介绍了[（ArO）-Ar-R）（3）tacn）U]-体系的三个重要反应，它们分别导致烷烃配位、CO/CO2活化和氮原子转移化学。
Electron-rich uranium coordination complexes display a pronounced reactivity toward small molecules. In this Feature article, the exciting chemistry of trivalent uranium ions coordinated to classic Werner-type ligand environments is reviewed. Three fundamentally important reactions of the [(((ArO)-Ar-R)(3)tacn)U]- system are presented that result in alkane coordination, CO/CO2 activation, and nitrogen atom-transfer chemistry.