Synthesis and optical properties of a bis(diphenylphosphino)dithienosilole‐digold(I) complex
Synthesis and optical properties of a bis(diphenylphosphino)dithienosilole‐digold(I) complex
复制标题
双(二苯基膦)二噻吩并硅咯-二金(I)配合物的合成及光学性质
DOI：
10.1002/hc.20715
复制
发表时间：
2011
影响因子：
0.3
通讯作者：
H. Higashimura
中科院分区：
文献类型：
--
作者：
J. Ohshita;Yuta Tominaga;T. Mizumo;Yusuke Kuramochi;H. Higashimura
2，6-bis(diphenylphosphino)-4，4-bis(4-n-butylphenyl)dithienosilole与氯代二甲基硫化金(I)在丙酮中反应，得到淡绿色固体。该络合物具有较高的发射率，表现出蓝色光致发光，其溶液和粉末的量子效率Φ分别为0.99和0.30。该络合物表现出良好的成膜性能，其在甲苯溶液中的旋涂提供了一种薄的固体薄膜，该薄膜也具有发射性能，Φ=0.082011Wiley Percials，Inc.杂原子化学22：514-517,2011；请访问Wileyonlinelibrary.com在线查看本文。DOI 10.1002/hc.20715
Treatment of 2,6-bis(diphenylphosphino)-4,4-bis(4-n-butylphenyl)dithienosilole with chloro(dimethylsulfide)gold(I) in acetone gave the corresponding digold complex as pale green solids. The complex was highly emissive and showed blue photoluminescence with the quantum efficiencies of Φ = 0.99 and 0.30 for its solution and powders, respectively. The complex showed good film forming properties and its spin coating from the toluene solution afforded a thin solid film that also showed emissive properties with Φ = 0.08 © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:514–517, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20715
3,4,6-三苯基-α-吡喃酮的光学和电致发光性质
DOI：
--
发表时间：
2006
期刊：
J. Phys. and Chem. of Solids 67・11
影响因子：
--
作者：
Z.Kin;H.Kajii;Y.Ohmori;M.Komatsu;S.Minakata;M.Tsumura;K.Namura
通讯作者：
K.Namura