Preparation, characterization and application of KNH2/Al2O3 and KF/Al2O3 as strong solid bases
Preparation, characterization and application of KNH2/Al2O3 and KF/Al2O3 as strong solid bases
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DOI：
10.1002/chin.200126236
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发表时间：
2000-03
期刊：
影响因子：
--
通讯作者：
T. Baba
中科院分区：
文献类型：
--
作者：
T. Baba
本文综述了负载氧化铝的KNH2和负载氧化铝的KF的制备、表征及其应用。这些强固体碱以非常选择性的方式催化各种有机反应。这些反应包括烯烃和炔烃的异构化反应、炔烃的二聚化反应、铁先科反应以及硅烷形成Si-C、Si-N和Si-O键的反应。
This review describes the preparation, characterization and application of KNH2 loaded on alumina and KF loaded on alumina. These strong solid bases catalyze a variety of organic reactions in a very selective manner. The reactions include isomerizations of alkenes and alkynes, dimerization of alkynes, Tishchenko reaction, and the reaction of silanes to form of Si–C, Si–N and Si–O bonds.