Direct assembly synthesis of metal complex-semiconductor hybrid photocatalysts anchored by phosphonate for highly efficient CO2 reduction.
Direct assembly synthesis of metal complex-semiconductor hybrid photocatalysts anchored by phosphonate for highly efficient CO2 reduction.
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DOI：
10.1039/c1cc12491a
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发表时间：
2011-07
影响因子：
4.9
通讯作者：
Tomiko M. Suzuki;Hiromitsu Tanaka;T. Morikawa;M. Iwaki;Shunsuke Sato;S. Saeki;Masae Inoue;T. Kajino;T. Motohiro
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文献类型：
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作者：
Tomiko M. Suzuki;Hiromitsu Tanaka;T. Morikawa;M. Iwaki;Shunsuke Sato;S. Saeki;Masae Inoue;T. Kajino;T. Motohiro
采用直接组装法成功地合成了由钌配合物和有机基团锚定的p型光活性N掺杂Ta（2）O（5）组成的杂化光催化剂。在可见光照射下，该光催化剂在反应速率和稳定性方面表现出优异的CO（2）转化为甲酸的光催化活性。
Hybrid photocatalysts consisting of a ruthenium complex and p-type photoactive N-doped Ta(2)O(5) anchored with an organic group were successfully synthesized by a direct assembly method. The photocatalyst anchored by phosphonate exhibited excellent photoconversion activity of CO(2) to formic acid under visible-light irradiation with respect to the reaction rate and stability.