Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis
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DOI：
10.1021/acscatal.0c02849.s001
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发表时间：
2020-07
期刊：
影响因子：
12.9
通讯作者：
Yuki Kakeno;Mayu Kusakabe;K. Nagao;H. Ohmiya
中科院分区：
文献类型：
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作者：
Yuki Kakeno;Mayu Kusakabe;K. Nagao;H. Ohmiya
以脂肪醛为酰基给体，设计合成了一种含N-新戊基和七元主链结构的噻唑鎓型N-杂环卡宾（NHC）催化剂。
A designed thiazolium-type N-heterocyclic carbene (NHC) catalyst having an N-neopentyl group and seven-membered backbone structure was achieved through the use of aliphatic aldehydes as acyl donors...