Second harmonic generation properties of Ca3(O3C3N3)2 ‐Sr3(O3C3N3)2 solid solutions
Second harmonic generation properties of Ca3(O3C3N3)2 ‐Sr3(O3C3N3)2 solid solutions
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DOI：
10.1002/crat.201600029
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发表时间：
2016-07
影响因子：
1.5
通讯作者：
Markus J. Kalmutzki;Xiao Wang;A. Meixner;H. Meyer
中科院分区：
文献类型：
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作者：
Markus J. Kalmutzki;Xiao Wang;A. Meixner;H. Meyer
在525 °C下，通过放热固态复分解反应，制备了二次谐波发生材料Ca 3（O3 C3 N3）2（CCY）和Sr 3（O3 C3 N3）2（SCY）的固溶体。报道了由连续阳离子取代引起的SHG强度的变化。用差热分析法研究了SCY-K（OCN）相图作为SCY晶体生长介质的可能性。
Solid solutions of the second harmonic generation (SHG) materials Ca3(O3C3N3)2 (CCY) and Sr3(O3C3N3)2 (SCY) were prepared via exothermic solid state metathesis reactions from appropriate amounts of the corresponding metal chlorides and potassium cyanate at 525 °C. The change in SHG intensity caused by the successive cation substitution is reported. Differential thermal analyses are used to explore the SCY–K(OCN) phase diagram as a medium for the growth of SCY crystals.