Pd Nanoparticles Supported on Amine-Functionalized MgAl Layered Double Hydroxides for Solvent-Free Aerobic Oxidation of Benzyl Alcohol
Pd Nanoparticles Supported on Amine-Functionalized MgAl Layered Double Hydroxides for Solvent-Free Aerobic Oxidation of Benzyl Alcohol
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胺功能化镁铝层状双氢氧化物负载钯纳米粒子用于苯甲醇无溶剂有氧氧化
DOI：
10.3390/catal9121038
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发表时间：
2019-12
期刊：
影响因子：
3.9
通讯作者：
Li Ruifeng
中科院分区：
文献类型：
--
作者：
Shi Xiufeng;Xing Bin;Guo Wenya;Zhang Huifang;Fan Binbin;Li Ruifeng
Pd nanoparticles (NPs) supported on amine-functionalized layered double hydroxides (LDHs) (Pd/NH2-LDH-NS) were successfully obtained by implanting aminopropyltriethoxysilane (APTS) on MgAl LDH nanosheets (LDH-NS), followed by impregnating [Pd(NH3)4]Cl2 and reduction with NaBH4. The physicochemical characteristics of the obtained Pd/NH2-LDH-NS were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR),, N2 adsorption–desorption, inductive coupled plasma (ICP), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy(XPS), and their catalytic performance was tested in the selective oxidation of benzyl alcohol with molecular oxygen under solvent-free and base-free conditions. The results showed that the implanted –NH2 groups can promote the dispersion of the supported Pd NPs via complexation of the implanted –NH2 groups to Pd NPs, and they can increase the surface basicity of the catalysts, thus enhancing the catalytic activity and selectivity to benzylaldehyde. Pd/NH2-LDH-NS exhibited enhanced catalytic activity (31.6%) and selectivity (>98%) compared to the corresponding Pd/LDH-NS, Pd/LDH, Pd/SiO2, and Pd/Al2O3. Moreover, Pd/NH2-LDH-NS was remarkably stable and could be reused at least four times without a significant loss in activity and selectivity.
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DOI：
10.1002/chin.201450233
发表时间：
2014-12
期刊：
ChemInform
影响因子：
--
作者：
Guoli Fan;Feng Li;D. Evans;X. Duan
通讯作者：
Guoli Fan;Feng Li;D. Evans;X. Duan
MnO2 纳米棒负载的金纳米颗粒具有增强的无溶剂需氧酒精氧化活性
影响因子：
3.7
作者：
Wang, Lu-Cun;Liu, Yong-Mei;Fan, Kang-Nian
通讯作者：
Fan, Kang-Nian
影响因子：
5.5
作者：
Guadix-Montero, Susana;Alshammari, Hamed;Sankar, Meenakshisundaram
通讯作者：
Sankar, Meenakshisundaram
影响因子：
8.4
作者：
R. Naik;A. Nizam;Aisha Siddekha;M. A. Pasha
通讯作者：
R. Naik;A. Nizam;Aisha Siddekha;M. A. Pasha
影响因子：
3.3
作者：
Dimitratos, Nikolaos;Lopez-Sanchez, Jose Antonio;Hutchings, Graham J.
通讯作者：
Hutchings, Graham J.