Hydrothermal Synthesis of Interstratified Lizardite/Saponite

Hydrothermal Synthesis of Interstratified Lizardite/Saponite
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层间蜥蜴石/皂石的水热合成

DOI:
10.1111/j.1151-2916.1998.tb02358.x
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发表时间:
2005
影响因子:
3.9
通讯作者:
T. Iwasaki
T. Iwasaki
中科院分区:
材料科学2区
文献类型:
--
作者:
K. Torii;Y. Onodera;H. Hayashi;Nagase Takako;T. Iwasaki

文献摘要

被引文献

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以硅铝镁均匀凝胶为原料,在300℃下水热合成了一种自然界中从未发现的新型间层状蜥蜴石/皂石。结构中蜥蜴石层与皂土层的堆积比设计为3/1 ~ 1/3。这些材料根据层的组成给出部分有序的x射线衍射图。L/S= 1/1样品的晶格条纹图像显示,血小板颗粒的厚度为17.5 a,由蜥蜴石层(7.5 a)和脱水皂土层(10.0 a)组成。它们可以像蒙脱石一样分散在水中。
A novel interstratified lizardite/saponite which has never been found in nature is hydrothermally synthesized from uniform Si-Al-Mg gels at 300°C. The stacking ratios of lizardite layer to saponite layer in the structure are designed between 3/1 and 1/3. These materials give partially ordered X-ray diffraction patterns depending on the layer composition. The lattice-fringe image of the L/S= 1/1 sample shows that platelet particles have a thickness of 17.5 A consisting of a lizardite layer (7.5 A) and a dehydrated saponite layer (10.0 A). They can disperse in water like smectite.