Preparation of Metallic Films by Electrodeposition at the Interface between Two Liquid Phases
Preparation of Metallic Films by Electrodeposition at the Interface between Two Liquid Phases
复制标题
两液相界面电沉积制备金属薄膜
DOI：
10.2320/matertrans1989.34.732
复制
发表时间：
1993
期刊：
影响因子：
--
通讯作者：
H. Sakahara
中科院分区：
文献类型：
--
作者：
H. Kaneko;H. Taimatsu;H. Sakahara
一种连续获得金属膜的新技术，在有机液体和金属盐的水溶液之间的界面处通过电解产生金属膜，并将沿界面沿着单向生长的膜滚动到旋转滚筒上。例如，锌膜生长在乙酸正丁酯/硫酸锌溶液界面处。薄膜厚度约为1 μm，生长方向平行于锌的基面。讨论了影响金属膜形成的一些因素
A novel technique is described for continuously obtaining metallic films: a metallic film is produced by electrolysis at the interface between an organic liquid and an aqueous solution of a metal salt, and the film growing uni-directionally along the interface is rolled onto a rotating drum. As an example, zinc films are grown at the n-butyl acetate/zinc sulfate solution interface. The zinc films have a thickness of about 1 μm, and their growth directions are parallel to the basal plane of zinc. Some factors governing the metallic film formation are discussed