1,8,17,24-Tetraoxa[8.8](2,6)naphthalenophane-3,5,19,21-tetrayne-10,30-dicarboxylic acid derivatives, novel complexors of aromatic guests
1,8,17,24-Tetraoxa[8.8](2,6)naphthalenophane-3,5,19,21-tetrayne-10,30-dicarboxylic acid derivatives, novel complexors of aromatic guests
复制标题
1,8,17,24-四氧杂[8.8](2,6)萘芬-3,5,19,21-四炔-10,30-二甲酸衍生物，新型芳香客体络合剂
DOI：
10.1021/ja00389a050
复制
发表时间：
1982
影响因子：
15
通讯作者：
H. Whitlock
中科院分区：
文献类型：
--
作者：
E. T. Jarvi;H. Whitlock
Synthesisand complexation behavior of the title molecules are described. Study of the aromatic solvent-induced shifts of these molecules supports thecontention that their large cavity can accommodate aromatic rings. The behavior of acid la in water suggests that this effect is enhanced in aqueous medium, as is expected for formation of hydrophobic inclusion complexes. In contrast to the rigid naphthalenophanes (1), their saturated derivatives (7) exist in a collapsed conformation and do not incorporate aromatic guests.
