Recognition of polyimide sequence information by a molecular tweezer
Recognition of polyimide sequence information by a molecular tweezer
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DOI：
10.1002/anie.200460382
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发表时间：
2004-01-01
影响因子：
16.6
通讯作者：
Zhu, ZX
中科院分区：
文献类型：
--
作者：
Colquhoun, HM;Zhu, ZX
芳香族共聚酰亚胺中的特定单体序列是通过它们与空间和电子互补的分子钳的相互作用来识别的。这些相互作用使得镊子分子能够通过与聚合物链上的相邻位点的多个相邻结合来读取包含多达27个芳环的单体序列。
Specific monomer sequences in aromatic copolyimides are recognized through their -stacking and hydrogen-bonding interactions with a sterically and electronically complementary molecular tweezer. These interactions enable the tweezer molecule to read monomer sequences comprising up to 27 aromatic rings by multiple adjacent binding to neighboring sites on the polymer chain.