Rational materials design of sorbent coatings for explosives: applications with chemical sensors
Rational materials design of sorbent coatings for explosives: applications with chemical sensors
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DOI：
10.1016/s0039-9140(00)00545-2
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发表时间：
2001-05-10
期刊：
影响因子：
6.1
通讯作者：
McGill, RA
中科院分区：
文献类型：
--
作者：
Houser, EJ;Mlsna, TE;McGill, RA
设计合成了一系列化学选择性聚合物，以提高聚合物涂层化学传感器对多硝基芳烃分析物的吸附性能。为了评估化学选择性涂层的有效性，利用多硝基芳香族蒸气测试床来挑战具有不同爆炸性蒸气的聚合物涂覆的表面声波（SAW）装置。二硝基甲苯的检测限被确定为< 100万亿分之一。ATR-FTIR研究用于确定聚合物-多硝基芳族分析物相互作用的性质，并确认聚合物侧基和多硝基芳族爆炸材料的硝基官能团之间存在氢键。(C)2001 Elsevier Science B. V.保留所有权利。
A series of chemoselective polymers had been designed and synthesized to enhance the sorption properties of polymer coated chemical sensors for polynitroaromatic analytes. To evaluate the effectiveness of the chemoselective coatings, a polynitroaromatic vapor test bed was utilized to challenge polymer coated surface acoustic wave (SAW) devices with different explosive vapors. Dinitrotoluene detection limits were determined to be in the < 100 parts per trillion ranges. ATR-FTIR studies were used to determine the nature of the polymer-polynitroaromatic analyte interactions, and confirm the presence of hydrogen-bonding between polymer pendant groups and the nitro functional groups of polynitroaromatic explosive materials. (C) 2001 Elsevier Science B.V. All rights reserved.