Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs
Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs
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DOI：
10.1039/c2ce26395e
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发表时间：
2013-01-01
期刊：
影响因子：
3.1
通讯作者：
Gerasimchuk, Nikolay
中科院分区：
文献类型：
--
作者：
Curtis, Scott;Ilkun, Olesya;Gerasimchuk, Nikolay
合成了两种新的双氰肟异构体，并通过紫外可见、红外、核磁共振、pK(a)测量和x射线分析等多种光谱方法对其进行了表征。这些合成的化合物代表了第一个非螯合的双氰肟，可以作为新的mof样结构的基石。
Two new isomeric bis-cyanoximes were synthesized and characterized by a variety of spectroscopic methods including UV-visible, infrared, NMR, pK(a) measurements and X-ray analysis. These synthesized compounds represent the first non-chelating bis-cyanoximes that can function as building blocks for new MOF-like structures.