MEDIUM EFFECTS ON THE POLYMERIZATION EFFICIENCY OF A CHOLESTERYL-BEARING METHACRYLATE MONOMER
MEDIUM EFFECTS ON THE POLYMERIZATION EFFICIENCY OF A CHOLESTERYL-BEARING METHACRYLATE MONOMER
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DOI：
10.1021/ma00056a030
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发表时间：
1993-02-15
期刊：
影响因子：
5.5
通讯作者：
GRIFFIN, AC
中科院分区：
文献类型：
--
作者：
HOYLE, CE;CHAWLA, CP;GRIFFIN, AC
使用专门设计的 DSC 放热装置，用稳态灯和脉冲激光对含胆固醇液晶甲基丙烯酸酯单体进行光聚合。聚合动力学受聚合过程中发生的介质变化的影响。液晶单体在光学显微镜热台中的光聚合给出了与 DSC 放热单元中的光聚合相关的结果。
Photopolymerization of a cholesteryl-containing liquid crystalline methacrylate monomer with both a steady-state lamp and a pulsed laser has been followed by using a specially designed DSC exotherm unit The polymerization kinetics are affected by changes in the medium occurring during the polymerization process. Photopolymerization of the liquid crystalline monomer in the hot stage of an optical microscope gives results which correlate with the photopolymerization in the DSC exotherm unit.