Probing properties of molecule-based interface systems: general discussion and Discussion of the Concluding Remarks.
Probing properties of molecule-based interface systems: general discussion and Discussion of the Concluding Remarks.
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基于分子的界面系统的探测特性：一般讨论和结论性讨论。
DOI：
10.1039/c7fd90077e
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发表时间：
2017
影响因子：
3.4
通讯作者：
Amabilino D
中科院分区：
文献类型：
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作者：
Amabilino D
安吉丽卡·昆勒回答道：谢谢你的问题。我们目前正在研究温度对距离分布的影响。原则上，有两种影响：在低温下，分子可能没有足够的流动性，条纹不会达到它们的最佳位置。因此，分布将具有更大的标准差。对于高温，也可以访问“激发态”，即，由于排斥在能量格局中的小调制可能在特定温度以上是无法检测到的。Ioan BˆAldea说：也许在实验直方图中(例如，图3A-C中的蓝色条，DOI：10.1039/C7FD00089H)，你可以将物理效应(S)从几何效应(那些图中的灰色条)中分离出来，并专注于前者(T依赖)。无论如何，对于一个想要与你的数据进行比较的理论家来说，展示温度对距离直方图的影响的量化结果也是很有趣的。
Angelika Kühnle replied: Thanks for the question. We are currently investigating the impact of temperature on the distance distributions. In principle, there are two effects: at low temperatures, the molecules might not be mobile enough and the stripes will not adopt their optimum position. Thus, the distribution will have a larger standard deviation. For elevated temperatures,“excited states” can also be accessed, ie, a small modulation in the energy landscape due to repulsion might not be detectable above a certain temperature.Ioan Bˆaldea said: Maybe in the experimental histograms (eg the blue bars in Fig. 3a–c, DOI: 10.1039/C7FD00089H) you can disentangle the physical effect (s) from the geometrical effects (grey bars in those gures) and focus on the (T-dependence of the) former. Anyway, presenting quantitative results on the effect of temperature on distance histograms would be interesting also for a theorist aiming to compare with your data.
六噻吩在Si(111)-√3×√3-Ag表面的吸附和自组装结构。
DOI：
10.1063/1.4921568
发表时间：
2015
期刊：
The Journal of chemical physics
影响因子：
--
作者：
T. Yokoyama;M. Kawasaki;T. Asari;S. Ohno;Masatoshi Tanaka;Y. Yoshimoto
通讯作者：
Y. Yoshimoto