Mirror Symmetry Breaking by Mixing of Equimolar Amounts of Two Gyroid Phase- Forming Achiral Molecules
Mirror Symmetry Breaking by Mixing of Equimolar Amounts of Two Gyroid Phase- Forming Achiral Molecules
复制标题
等摩尔量的两个螺旋相形成非手性分子混合打破镜面对称
DOI：
10.1039/c6cp02954j
复制
发表时间：
2016
期刊：
影响因子：
--
通讯作者：
Y. Yamamura & K. Saito
中科院分区：
文献类型：
--
作者：
S. Kutsumizu;S. Miisako;Y. Miwa;M. Kitagawa;Y. Yamamura & K. Saito
镜像对称性破缺是通过混合等摩尔量的两个螺旋形相形成的非手性分子，一个具有短的和另一个具有长的尾巴。这一事实表明了临界链长对于手性双连续立方相（Cubbi）的出现的重要性。它还表明，分子水平的流动性是密切相关的这些Cubbi相的形成和稳定。
Mirror symmetry breaking was observed by mixing of equimolar amounts of two gyroid phase-forming achiral molecules, one having a short and the other with a long tail. This fact indicates the importance of a critical chain length for the appearance of the chiral bicontinuous cubic (Cubbi) phase. It also demonstrates that the molecular-level mobility is closely connected to the formation and stabilisation of those Cubbi phases.