Isolation, Structure Elucidation, and Total Synthesis of Two New Chimonanthus Alkaloids, Chimonamidine and Chimonanthidine.

Isolation, Structure Elucidation, and Total Synthesis of Two New Chimonanthus Alkaloids, Chimonamidine and Chimonanthidine.
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DOI:
10.1002/chin.200423216
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发表时间:
2004-01
期刊:
ChemInform
影响因子:
--
通讯作者:
H. Takayama;Yohei Matsuda;K. Masubuchi;Atsushi Ishida;M. Kitajima;N. Aimi
H. Takayama;Yohei Matsuda;K. Masubuchi;Atsushi Ishida;M. Kitajima;N. Aimi
中科院分区:
其他
文献类型:
--
作者:
H. Takayama;Yohei Matsuda;K. Masubuchi;Atsushi Ishida;M. Kitajima;N. Aimi

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从腊梅种子中分离出两种新的色胺相关生物碱:腊梅脒和腊梅花啶。通过光谱分析和色胺仿生全合成阐明了它们的结构,包括绝对构型。
Two new tryptamine-related alkaloids, chimonamidine and chimonanthidine, were isolated from the seeds of Chimonanthus praecox Link. and their structures including absolute configuration were elucidated by spectroscopic analysis and biomimetic total synthesis from tryptamine.