Alkali metal-mediated proline aggregation in solution observed by coldspray ionization mass spectrometry.

Alkali metal-mediated proline aggregation in solution observed by coldspray ionization mass spectrometry.
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通过冷喷雾电离质谱法观察溶液中碱金属介导的脯氨酸聚集。

DOI:
10.1021/ol017028f
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发表时间:
2002
期刊:
影响因子:
5.2
通讯作者:
K. Yamaguchi
K. Yamaguchi
中科院分区:
化学1区
文献类型:
--
作者:
Miki Kunimura;S. Sakamoto;K. Yamaguchi

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l -脯氨酸在溶液中碱金属离子存在时聚集形成环状团簇,而其他几种氨基酸则观察到大规模的聚集链结构。根据冷喷雾电离质谱直接溶液分析,认为主要的环状团簇是由三聚体和四聚体亚基构成的。
L-Proline aggregates to form cyclic clusters in the presence of alkali metal ions in solution, whereas a large-scale-aggregated chain structure was observed for several other amino acids. The major cyclic clusters are suggested to be constructed from trimeric and tetrameric subunits on the basis of direct solution analysis by coldspray ionization mass spectrometry.
DOI: 10.1021/ja003043o
发表时间: 2001-02-07
影响因子: 15
作者:
Yamanoi, Y;Sakamoto, Y;Yamaguchi, K
通讯作者: Yamaguchi, K