Ostwald's rule and enantiotropy: polymorph appearance in the crystallisation of p-aminobenzoic acid
Ostwald's rule and enantiotropy: polymorph appearance in the crystallisation of p-aminobenzoic acid
复制标题
DOI：
10.1039/c5ce00353a
复制
发表时间：
2015-07
期刊：
影响因子：
3.1
通讯作者：
James F. B. Black;R. Davey;R. Gowers;A. Yeoh
中科院分区：
文献类型：
--
作者：
James F. B. Black;R. Davey;R. Gowers;A. Yeoh
多晶型体系中合理结晶策略的开发需要动力学和热力学的实验操作。我们第一次展示了这些竞争驱动力之间的相互作用的结果在一个互变系统，对氨基苯甲酸。结果是非预期的，温度没有影响。
The development of rational crystallisation strategies in polymorphic systems requires the experimental manipulation of both kinetics and thermodynamics. We show for the first time the results of the interplay between these competing driving forces in an enantiotropic system, p-aminobenzoic acid. The outcomes are unexpected with temperature having no impact.