Synthesis of Comblike Poly(methyl methacrylate) by Atom Transfer Radical Polymerization with Poly(ethyl 2-bromoacrylate) as Macroinitiator

Synthesis of Comblike Poly(methyl methacrylate) by Atom Transfer Radical Polymerization with Poly(ethyl 2-bromoacrylate) as Macroinitiator
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发表时间:
2003
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通讯作者:
YanShi;Zhi-fengFu;YuDongZHANG;Shu-keJiao
YanShi;Zhi-fengFu;YuDongZHANG;Shu-keJiao
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其他
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作者:
YanShi;Zhi-fengFu;YuDongZHANG;Shu-keJiao

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以聚2-溴代丙烯酸乙酯为大分子引发剂,通过原子转移自由基聚合法合成了梳状聚甲基丙烯酸甲酯。用凝胶渗透色谱(GPC)和核磁共振氢谱对所得梳状聚合物进行了表征。
Comblike poly(methyl methacrylate) was synthesized by atom transfer radical polymerization of methyl methacrylate with poly(ethyl 2-bromoacrylate) as a macroinitiator, which was prepared by conventional free radical polymerization of ethyl 2-bromoacrylate. The obtained comblike polymers were characterized by GPC and 1H NMR.