Transformation between monovalent and divalent ionic solids:: An ionic(I)ionic(II) phase transition in a biferrocene-F1TCNQ charge-transfer complex
Transformation between monovalent and divalent ionic solids:: An ionic(I)ionic(II) phase transition in a biferrocene-F1TCNQ charge-transfer complex
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DOI：
10.1143/jpsj.74.2214
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发表时间：
2005-08-01
影响因子：
1.7
通讯作者：
Sujawara, T
中科院分区：
文献类型：
--
作者：
Mochida, T;Takazawa, K;Sujawara, T
一个“离子（l）。在由二新戊基双二茂铁（D）和氟四氰基醌二甲烷（A）组成的新分子固体中观察到离子（II）”电荷转移跃迁。该材料在室温下为一价固体（D（+）A（3）（-）），在低温下转变为二价固体（（D2+ At 32）），并在120 K附近发生一级相变。
An "ionic(l).-ionic(II)" charge-transfer transition has been observed in a new molecular solid composed of dineopentylbiferrocene (D) and fluorotetraicyanoquinodimethane i (A). The material is a monovalent solid (D(+)A(3)(-)) at room temperature and Changes to a divalent solid ((D2+At32)) at low temperatures, in association with a broad first-order phase transition it around 120 K.