Copper-catalyzed Silylative Allylation of Ketones and Aldehydes Employing Allenes and Silylboranes
Copper-catalyzed Silylative Allylation of Ketones and Aldehydes Employing Allenes and Silylboranes
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DOI：
10.1246/cl.141018
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发表时间：
2015-03
影响因子：
1.6
通讯作者：
Yosuke Tani;Tatsuya Yamaguchi;Tetsuaki Fujihara;J. Terao;Y. Tsuji
中科院分区：
文献类型：
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作者：
Yosuke Tani;Tatsuya Yamaguchi;Tetsuaki Fujihara;J. Terao;Y. Tsuji
研究了铜催化的酮与联烯和硅基硼烷的硅烷基化烯丙基化反应，反应中原位生成了β-硅烷基烯丙基铜中间体。各种酮类和联烯类化合物也被发现。
The copper-catalyzed silylative allylation of ketones with allenes and silylboranes via an in situ generated β-silylallylcopper intermediate has been developed. Various ketones and allenes were con...