In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions
In situ investigations of the polyoxometalate Trojan Horse compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O under high temperature and high pressure conditions
复制标题
高温高压下多金属氧酸盐木马化合物K7Na[WVI18O56(SO3)2(H2O)2]·20H2O的原位研究
作者：
Cabrera R
用拉曼光谱和红外光谱研究了具有Wells-Dawson型结构的多金属氧酸盐化合物K7Na[WVI18O56(SO3)2(H2O)2]·20H2O中亚硫酸盐基团在高温高压下的氧化反应。这些结果使人们对这种化合物中发生的不寻常的氧化还原过程有了新的见解，电子和O2−离子在笼子内的多金属氧酸盐簇和SO32−/SO42−基团之间转移，这一过程被称为“特洛伊木马”效应。
We have used Raman and IR spectroscopy to study the oxidation reaction of sulfite groups in the unique polyoxometalate compound K7Na[WVI18O56(SO3)2(H2O)2]·20H2O with a structure related to the Wells–Dawson type in situ at high temperature and high pressure. The results give new insights into the unusual redox process that occurs in this compound with electrons and O2− ions transferred between the polyoxometalate cluster and SO32−/SO42− groups held within the cage in a process that has been termed the “Trojan Horse” effect.
多硫代钼轮作为阴离子受体识别硫酸根和磺酸根阴离子
DOI：
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发表时间：
2009
期刊：
影响因子：
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作者：
Jean;Sébastien Floquet;J. Marrot;E. Cadot
通讯作者：
E. Cadot