Third ionization potentials and sublimation energies of the lanthanides

Third ionization potentials and sublimation energies of the lanthanides
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镧系元素的第三电离势和升华能

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发表时间:
1969
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影响因子:
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通讯作者:
David A Johnson
David A Johnson
中科院分区:
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文献类型:
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作者:
David A Johnson

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A simple ionic crystal model is used in conjunction with the Born–Haber cycle and auxiliary thermodynamic data to deduce the nature of the variations in the third ionization potential across the lanthanide series. The variation is consistent with the theory of atomic spectra. The similarities between the changes in –I3 and those in the sublimation energies of the metals are also discussed.