Can heterometallic 1-dimensional chains support current rectification?
Can heterometallic 1-dimensional chains support current rectification?
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DOI：
10.1039/c3cc45063e
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发表时间：
2013-09
影响因子：
4.9
通讯作者：
Daniel DeBrincat;Oliver Keers;J. McGrady
中科院分区：
文献类型：
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作者：
Daniel DeBrincat;Oliver Keers;J. McGrady
过渡金属离子的异金属链在多大程度上可以产生不对称的电流-电压响应？密度泛函理论表明，答案在很大程度上取决于主导传导通道的对称性：π通道更局部化，因此提供更高的整流比。
To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios.