Synthesis of Novel Benzobacteriopurpurins by Diels-Alder Cycloaddition
Synthesis of Novel Benzobacteriopurpurins by Diels-Alder Cycloaddition
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Diels-Alder环加成法合成新型苯并细菌红紫素
DOI：
10.1246/cl.1996.1119
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发表时间：
1996
影响因子：
1.6
通讯作者：
R. Pandey
中科院分区：
文献类型：
--
作者：
G. Zheng;A. Kozyrev;T. Dougherty;Kevin M Smith;R. Pandey
以8-乙烯基介孔紫红素-18甲酯为原料，与四氰乙烯(TCNE)和乙酰二甲酸二甲酯(DMAD)进行Diels-Alder环加成反应，合成了一类新的稳定的细菌素，即含两个外环的苯并细菌紫红素。这些新型细菌素在760-795 nm范围内具有长波吸收。
A new class of stable bacteriochlorins, namely benzobacteriopurpurin bearing two exo-cyclic rings was synthesized by way of Diels-Alder cycloaddition of 8-vinyl-mesopurpurin-18 methyl ester with tetracyanoethylene (TCNE) and dimethyl acetylenedicarboxylate (DMAD). These novel bacteriochlorins have long wavelength absorptions in the range of 760 to 795 nm.
DOI：
10.1016/1011-1344(91)80016-b
发表时间：
1991-09-01
影响因子：
5.4
作者：
HENDERSON, BW;SUMLIN, AB;DOUGHERTY, TJ
通讯作者：
DOUGHERTY, TJ