Palladium-catalyzed Dehydrogenative [3+3] Aromatization of Propyl Ketones and Allyl Carbonates
Palladium-catalyzed Dehydrogenative [3+3] Aromatization of Propyl Ketones and Allyl Carbonates
复制标题
DOI：
10.1246/cl.220032
复制
发表时间：
2022-04-01
影响因子：
1.6
通讯作者：
Ueno, Satoshi
中科院分区：
文献类型：
--
作者：
Koike, Kenta;Ueno, Satoshi
研究了Pd催化的3-苯丙酮和碳酸烯丙酯的[3+3]芳构化反应。该反应得到各种二或三取代的芳族酮。由五个步骤组成的反应在一个批次，一个操作设置中有效地进行。假定的活性物种，eta（3）-钯配合物，作为催化剂的三重异构化和单烯丙基化与高底物控制。
A Pd-catalyzed dehydrogenative [3+3] aromatization of 3-phenylpropyl ketones and allyl carbonates has been developed. The reaction gives various di- or tri-substituted aromatic ketones. The reaction consisting of five steps efficiently proceeded in a one-batch, one-manipulation setup. The postulated active species, eta(3)-palladium complex, works as a catalyst for triple dehydrogenations and mono allylation with high substrate controls.