SYNTHESIS OF A C-14,C-15 DIHYDRO DERIVATIVE OF THE SOUTH HEXACYCLIC STEROID UNIT OF CEPHALOSTATIN-1 .2. SPIROKETAL SYNTHESIS AND STEREOCHEMICAL ASSIGNMENT BY NMR-SPECTROSCOPY
SYNTHESIS OF A C-14,C-15 DIHYDRO DERIVATIVE OF THE SOUTH HEXACYCLIC STEROID UNIT OF CEPHALOSTATIN-1 .2. SPIROKETAL SYNTHESIS AND STEREOCHEMICAL ASSIGNMENT BY NMR-SPECTROSCOPY
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DOI：
10.1016/0040-4039(95)01805-r
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发表时间：
1995-11-13
影响因子：
1.8
通讯作者：
FUCHS, PL
中科院分区：
文献类型：
--
作者：
BHANDARU, S;FUCHS, PL
报道了将醛3转化为2，C-14‘，C-15’的头孢菌素11的‘’South‘’六环螺酮的二氢类似物。用核磁共振波谱分析了2的立体化学结构。
Transformation of aldehyde 3 into 2, a C-14',C-15' dihydro analog of the ''South'' hexacyclic spiroketal of cephalostatin 11 is described. The stereochemistry of 2 was elucidated by NMR spectroscopy.