Rhodium-Catalyzed Carbene-Transfer Reactions via Thienylcarbene Complexes Generated from Thiocarbamoyl-ene-yne Compounds
Rhodium-Catalyzed Carbene-Transfer Reactions via Thienylcarbene Complexes Generated from Thiocarbamoyl-ene-yne Compounds
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通过由硫代氨基甲酰基-烯-炔化合物生成的噻吩基卡宾配合物进行铑催化的卡宾转移反应
作者：
Tsuneishi;A.; Okamoto;K.;Ikeda;Y .; Murai;M.; Miki;K.; Ohe;K
催化噻吩基卡宾转移反应已被开发。以硫代氨甲酰基烯炔化合物为碳烯源，在铑催化下，烯烃、呋喃和噻吩的环丙烷化反应或杂环化合物的开环反应。这些方法为含噻吩的复杂分子提供了有效的合成方法。
Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules.