Comparison of Ru- and Mo-based chiral olefin metathesis catalysts. Complementarity in asymmetric ring-opening/cross-metathesis reactions of oxa- and azabicycles
Comparison of Ru- and Mo-based chiral olefin metathesis catalysts. Complementarity in asymmetric ring-opening/cross-metathesis reactions of oxa- and azabicycles
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DOI：
10.1021/ol071008h
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发表时间：
2007-07-19
期刊：
影响因子：
5.2
通讯作者：
Hoveyda, Amir H.
中科院分区：
文献类型：
--
作者：
Cortez, G. Alex;Baxter, Carl A.;Hoveyda, Amir H.
提出了手性 Mo 和 Ru 基催化剂通过不对称开环/交叉复分解 (AROM/CM) 反应促进对映选择性合成 2,6-二取代吡喃和哌啶的比较研究。这些研究证明了两类手性催化剂之间存在重要的互补性。
A comparative study of chiral Mo- and Ru-based catalysts to promote enantioselective synthesis of 2,6-disubstituted pyrans and piperidines through asymmetric ring-opening/cross-metathesis (AROM/CM) reactions is presented. These studies demonstrate the critical complementarity that exists between the two classes of chiral catalysts.