Synthesis of 1H-inden-1-ol derivatives via rhodium-catalyzed annulation of o-acylphenylboronic acids with alkynes
Synthesis of 1H-inden-1-ol derivatives via rhodium-catalyzed annulation of o-acylphenylboronic acids with alkynes
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DOI：
10.1246/cl.2005.1416
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发表时间：
2005-10-05
影响因子：
1.6
通讯作者：
Murakami, M
中科院分区：
文献类型：
--
作者：
Matsuda, T;Makino, M;Murakami, M
在室温下，铑催化邻甲酰苯硼酸与炔烃进行了区域选择性环化反应，得到取代的1h -吲哚-1-醇衍生物。邻乙酰苯硼酸也在80℃条件下进行环化反应，生成1-甲基- 1h -吲哚醇。
A rhodium-catalyzed annulation reaction of o-formylphenylboronic acid with alkynes occurred regioselectively at room temperature to give substituted 1H-inden-1-ol derivatives. o-Acetylphenylboronic acid also underwent the annulation reaction at 80 degrees C to afford 1-methyl-1H-inden-1-ols.