Core-polarization effects in the Cadmium isoelectronic sequence

Core-polarization effects in the Cadmium isoelectronic sequence
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镉等电子序列中的核心极化效应

DOI:
10.1103/physreva.62.032512
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发表时间:
2000
期刊:
影响因子:
2.9
通讯作者:
P. Quinet
P. Quinet
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
É. Biémont;C. Fischer;M. Godefroid;P. Palmeri;P. Quinet

文献摘要

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用相对论Hartree-Fock方法和多组态Dirac-Fock方法计算了镉等电子序列中允许和禁止自旋的5s{sup 2}{sup 1}-5s5p{sup 1,3}p{sub1}{sup o}57跃迁的振子强度,其中包括核-极化势和多组态Dirac-Fock方法,并考虑了价和核-价关联效应。当比较两组理论数据以及比较自旋禁忌跃迁的理论和实验时,注意到很好的一致性。单线态-单线态转变的理论(两种理论都是一致的)与实验之间的差异表明,一些实验数据需要修正。(C)2000年美国物理学会。
The oscillator strengths of the allowed and spin-forbidden 5s{sup 2} {sup 1}S{sub 0}-5s5p {sup 1,3}P{sub 1}{sup o} transitions in the cadmium isoelectronic sequence are evaluated for 48{<=}Z{<=}57 using the relativistic Hartree-Fock approach, including a core-polarization potential, and the multiconfiguration Dirac-Fock method, taking the valence and core-valence correlation effects into account. A good agreement is noted when comparing the two sets of theoretical data and when comparing theory with experiment for the spin-forbidden transition. The discrepancies observed between theory (both theories being in agreement) and experiment for the singlet-singlet transition indicate that some experimental data are in need of revision. (c) 2000 The American Physical Society.